Majority of technical details related to choosing voltage divider values into ADC figured out after taking into account the equivalent circuit in the ADC that contributes to the input impedance.
Finishing up LTspice simulation to try to validate proper equivalent input impedance after taking into account the shottky diode and low pass filter.
Still trying to figure out pros and cons in deciding to put RPP across the input voltage from the batteries or just the input into the 5V and 12V buck regulators.